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Relative Viscosity

Also known as: 相对粘度 · relative viskosität · relative viscosity · viscosidad relativa · RV · viscosidade relativa · intrinsic viscosity · inherent viscosity · solution viscosity

Material

Definition

Relative Viscosity (RV) is the ratio between the viscosity of a polymer solution and that of the pure solvent, measured under standard conditions (concentration, temperature). It is the most practical indicator of molecular weight of a resin and is used to certify polyamide (nylon) lots.

How it is measured

ISO 307 / ASTM D789:

  • Dissolve 0.5 – 1.0 g of resin in 100 mL of 90 % formic acid or 96 % sulfuric acid
  • Measure efflux time in an Ubbelohde viscometer at 25 °C
  • RV = t_solution / t_solvent

Typical values for PA (nylon)

  • PA 6 extrusion: RV 230 – 270 (high molecular weight)
  • PA 6 injection: RV 130 – 200 (low-to-medium molecular weight)
  • PA 66 injection: RV 40 – 80 (IV / Inherent Viscosity scale)
  • PA 12: RV 140 – 220

Why it matters in molding

  • High RV → stiff polymer, high mechanical strength, poorer flow (higher pressure, longer cycle)
  • Low RV → easy filling, ideal for thin or complex parts, but lower toughness
  • Selection depends on the part: technical engineers pick by RV, not MFI, because it correlates better with final properties.

Difference vs. MFI (Melt Flow Index)

MFI measures melt flow under standard load (g/10 min). RV measures molecular weight via solution viscosity. For PA, RV is more accurate and reproducible than MFI.

Common pitfalls

Mixing PA 6 RV with PA 66 RV (different scales), comparing supplier RV with different methods (formic vs. sulfuric), and forgetting that RV changes with absorbed moisture in PA before measurement.

Synonyms

viscosidade de solução
viscosité relative
löslichkeitsviskosität
solution viscosity
viscosity number

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