Definition
Relative Viscosity (RV) is the ratio between the viscosity of a polymer solution and that of the pure solvent, measured under standard conditions (concentration, temperature). It is the most practical indicator of molecular weight of a resin and is used to certify polyamide (nylon) lots.
How it is measured
ISO 307 / ASTM D789:
- Dissolve 0.5 – 1.0 g of resin in 100 mL of 90 % formic acid or 96 % sulfuric acid
- Measure efflux time in an Ubbelohde viscometer at 25 °C
- RV = t_solution / t_solvent
Typical values for PA (nylon)
- PA 6 extrusion: RV 230 – 270 (high molecular weight)
- PA 6 injection: RV 130 – 200 (low-to-medium molecular weight)
- PA 66 injection: RV 40 – 80 (IV / Inherent Viscosity scale)
- PA 12: RV 140 – 220
Why it matters in molding
- High RV → stiff polymer, high mechanical strength, poorer flow (higher pressure, longer cycle)
- Low RV → easy filling, ideal for thin or complex parts, but lower toughness
- Selection depends on the part: technical engineers pick by RV, not MFI, because it correlates better with final properties.
Difference vs. MFI (Melt Flow Index)
MFI measures melt flow under standard load (g/10 min). RV measures molecular weight via solution viscosity. For PA, RV is more accurate and reproducible than MFI.
Common pitfalls
Mixing PA 6 RV with PA 66 RV (different scales), comparing supplier RV with different methods (formic vs. sulfuric), and forgetting that RV changes with absorbed moisture in PA before measurement.
Synonyms